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sergei wrote:Although it will fool the oxygen sensor into reading that the mixture is leaner.
fuel wrote:What about carburettored cars or early NZ-new fuel injected cars (ie AE82 GT, Cordia turbo) which don't have O2 sensors as at that time they still had leaded fuel?
sergei wrote:In my opinion extra oxygen already bonded to Carbon/Hydrogen will not result in effect which are associated with leaner mixture, as when than oxygen breaks the bonds and makes new bonds, the nett result would be a (almost) no change of energy output, hence no detonation. Although it will fool the oxygen sensor into reading that the mixture is leaner.
Grrrrrrr! wrote:sergei wrote:In my opinion extra oxygen already bonded to Carbon/Hydrogen will not result in effect which are associated with leaner mixture, as when than oxygen breaks the bonds and makes new bonds, the nett result would be a (almost) no change of energy output, hence no detonation. Although it will fool the oxygen sensor into reading that the mixture is leaner.
Err, how do you fool an electro-chemical reaction? It wont be distracted by a nice set of legs
The O2 sensor will correctly read the amount of free oxygen in the exhaust gas stream, which be be higher when the engine is first run on bioethanol as it has a lower percentage of H & C available to bond to the oxygen in the intake charge.
Look at it another way.. for X amount of intake charge you get X amount of O2.. but when you add bioethanol you also add more Oxy with the fuel, which means there is more Oxy than the ecu expects and less HC with which to react it all. This results in some of the O2 going unused.
barryogen wrote:Somewhat weird though...
It would suggest that my car is fine with E3, with E5 I'd need to replace my fuel delivery system every 10 years or 100000kms, and E10 is a no-go... but the same model zze123 NZ New corolla is fine on it.
Have emailed Toyota about it... it seems a bit odd.
Octane (n-dodecane): C12H26 + 18.5 O2 → 12 CO2 + 13 H2O
18.5 x energy units.
Glucose via ethanol:
Glucose 2 C6H12O6 → 4 CO2 + 4 C2H5OH
Ethanol:4 C2H5OH + 12 O2 → 8 CO2 + 12 H2O
2 C6H12O6 + 12 O2 → 12 CO2 + 12 H2O
12.0 x energy units
By now you may have heard of the economic questions regarding using corn for ethanol production, but less attention has been paid to the environmental impact of using ethanol as an alternative to gasoline. Is ethanol more of a pollutant than gasoline? Surprisingly, the science says yes.
According to our Expert, who holds a PhD in Biochemical Engineering, a Master’s degree in Chemical Engineering, and has over 40 years experience performing biotechnology, bioengineering, and bioprocess research, both ethanol and gasoline deliver the same amount of carbon dioxide (CO2) into the atmosphere per gallon consumed. However, when compared on a per mile driven basis, burning ethanol actually produces 54% more CO2 as global warming pollutant than gasoline due to the fact that ethanol has lower fuel efficiency.
For the science buffs out there, the energy production produced by burning materials is proportional to the molecules of oxygen used. Here are the chemical formulas for the energy produced by burning octane via gasoline and by burning glucose via ethanol.
Octane (n-dodecane): C12H26 + 18.5 O2 → 12 CO2 + 13 H2O
18.5 x energy units.
Glucose via ethanol:
Glucose 2 C6H12O6 → 4 CO2 + 4 C2H5OH
Ethanol:4 C2H5OH + 12 O2 → 8 CO2 + 12 H2O
2 C6H12O6 + 12 O2 → 12 CO2 + 12 H2O
12.0 x energy units
toymachine wrote:I wonder if that this stage it's actually as much about emissions or making proper petrol last a bit longer?
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